Document Detail


Charge generation in low-polarity solvents: poly(ionic liquids)-functionalized particles.
MedLine Citation:
PMID:  23402544     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
We present a straightforward strategy for the synthesis of highly charged poly(ionic liquid)-functionalized particles in low-polarity solvents. A series of cationic liquid monomers consisting of a tetraalkyl ammonium cation and a fluorinated tetrakis[phenyl] borate anion linked, via a C$_{3}$-alkyl chain, to a methacrylate unit were synthesised. Addition of this ionic monomer to a conventional dispersion polymerization of methyl methacrylate and methacrylic acid at 80$\degc$ in a mixed dodecane/hexane solvent yielded spherical, highly monodisperse particles with mean diameters between $\sim$50 and 2500 nm with high electrophoretic mobility and stability in non-polar solvents such as dodecane. The surface potential in dodecane could be adjusted in the range from 0 to 180 $\pm$ 9 mV by altering the ratio of ionic monomer to methacrylate monomers. The particles open up new opportunities for the electrostatic assembly of nanoparticles and organized structures in non-polar environments.
Authors:
Ghulam Hussain; Amy Robinson; Paul Bartlett
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-2-12
Journal Detail:
Title:  Langmuir : the ACS journal of surfaces and colloids     Volume:  -     ISSN:  1520-5827     ISO Abbreviation:  Langmuir     Publication Date:  2013 Feb 
Date Detail:
Created Date:  2013-2-13     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9882736     Medline TA:  Langmuir     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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