Document Detail


Characterization of the triterpene saponins of the roots and rhizomes of blue cohosh (Caulophyllum thalictroides).
MedLine Citation:
PMID:  11743794     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Seven triterpene saponins were isolated from n-butanol fractions of blue cohosh (Caulophyllum thalictroides) roots and rhizomes. Their structures were established by spectral ((1)H NMR, (13)C NMR, 2D-NMR, and APCI-MS) techniques and chemical reactions as hederagenin 3-O-alpha-L-arabinopyranoside (1); caulophyllogenin 3-O-alpha-L-arabinopyranoside (2); hederagenin 3-O-beta-D-glucopyranosyl-(1-->2)-alpha-L-arabinopyranoside (3); 3-O-alpha-L-arabinopyranosyl-hederagenin 28-O-alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl(1-->6)-beta-D-glucopyranoside (4); 3-O-alpha-L-arabinopyranosyl- caulophyllogenin 28-O-alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl(1-->6)-beta-D-glucopyranoside (5); 3-O-beta-D-glucopyranosyl-(1-->2)-alpha-L-arabinopyranosyl- echinocystic acid 28-O-alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl(1-->6)-beta-D-glucopyranoside (6); 3-O-beta-D-glucopyranosyl-(1-->2)-alpha-L-arabinopyranosyl-hederagenin 28-O-alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl(1-->6)-beta-D-glucopyranoside (7). All seven compounds were identified in this species for the first time.
Authors:
J W Jhoo; S Sang; K He; X Cheng; N Zhu; R E Stark; Q Y Zheng; R T Rosen; C T Ho
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Journal of agricultural and food chemistry     Volume:  49     ISSN:  0021-8561     ISO Abbreviation:  J. Agric. Food Chem.     Publication Date:  2001 Dec 
Date Detail:
Created Date:  2001-12-17     Completed Date:  2002-02-26     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0374755     Medline TA:  J Agric Food Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  5969-74     Citation Subset:  IM    
Affiliation:
Department of Food Science and Center for Advanced Food Technology, Rutgers University, 65 Dudley Road, New Brunswick, New Jersey, 08901, USA.
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MeSH Terms
Descriptor/Qualifier:
Berberidaceae / chemistry*
Carbohydrate Sequence
Magnetic Resonance Spectroscopy
Models, Molecular
Molecular Conformation
Molecular Sequence Data
Oligosaccharides / chemistry
Plant Roots / chemistry
Rhizome / chemistry*
Saponins / analysis*
Triterpenes / analysis*
Chemical
Reg. No./Substance:
0/Oligosaccharides; 0/Saponins; 0/Triterpenes

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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