Document Detail


Catching Gaseous SO(2) in Cone-Type Lanthanide Complexes: An Unexpected Coordination Mode for SO(2) in f-Element Chemistry.
MedLine Citation:
PMID:  22473788     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Easy come, easy go: The first molecular SO(2) complexes of the lanthanides (Ln=Sm, Eu) are prepared. The compounds can reversibly coordinate gaseous SO(2) . Concomitant with the addition and removal of SO(2) , the color of the complexes changes reversibly. The structures of the SO(2) compounds could be confirmed in solution and in the solid state.
Authors:
Paul Benndorf; Sophia Schmitt; Ralf Köppe; Pascual Oña-Burgos; Andreas Scheurer; Karsten Meyer; Peter W Roesky
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-4-4
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  -     Publication Date:  2012 Apr 
Date Detail:
Created Date:  2012-4-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Institut für Anorganische Chemie, Karlsruher Institut für Technologie (KIT), Engesserstrasse 15, Geb. 30.45, 76131 Karlsruhe (Germany).
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