| Catalytic enantioselective aldol additions of alpha-isothiocyanato imides to alpha-ketoesters. | |
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MedLine Citation:
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PMID: 20485801 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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A readily available bifunctional thiourea catalyst promotes aldol additions of alpha-isothiocyanato imides to alpha-ketoesters under mild reaction conditions to form beta-hydroxy-alpha-amino acid derivatives with high levels of enantioselectivity. |
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Authors:
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Matthew K Vecchione; Le Li; Daniel Seidel |
Publication Detail:
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Type: Journal Article; Research Support, U.S. Gov't, Non-P.H.S. Date: 2010-05-19 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: 46 ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2010 Jul |
Date Detail:
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Created Date: 2010-06-17 Completed Date: 2010-09-13 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: England |
Other Details:
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Languages: eng Pagination: 4604-6 Citation Subset: IM |
Affiliation:
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Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, New Jersey 08854, USA. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Aldehydes
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chemistry* Amino Acids / chemical synthesis*, chemistry Catalysis Crystallography, X-Ray Esters / chemistry* Imides / chemistry* Ketones / chemistry* Models, Molecular Molecular Structure Stereoisomerism Thiourea / chemistry* |
| Chemical | |
Reg. No./Substance:
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0/Aldehydes; 0/Amino Acids; 0/Esters; 0/Imides; 0/Ketones; 62-56-6/Thiourea |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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