| Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base. | |
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MedLine Citation:
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PMID: 23328998 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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A base-free, catalytic protocol for the dehydrogenative Si-N coupling of weakly nucleophilic N-H groups of heteroarenes or aryl-substituted amines with equimolar amounts of hydrosilanes is reported. Cooperative Si-H bond activation at a Ru-S bond generates a silicon electrophile that forms a Si-N bond prior to the N-H deprotonation by an intermediate Ru-H complex, only releasing H(2). |
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Authors:
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C David F Königs; Maria F Müller; Nuria Aiguabella; Hendrik F T Klare; Martin Oestreich |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: 49 ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-01-24 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: England |
Other Details:
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Languages: eng Pagination: 1506-8 Citation Subset: IM |
Affiliation:
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Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 115, D-10623 Berlin, Germany. martin.oestreich@tu-berlin.de. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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