Document Detail

Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base.
MedLine Citation:
PMID:  23328998     Owner:  NLM     Status:  In-Data-Review    
A base-free, catalytic protocol for the dehydrogenative Si-N coupling of weakly nucleophilic N-H groups of heteroarenes or aryl-substituted amines with equimolar amounts of hydrosilanes is reported. Cooperative Si-H bond activation at a Ru-S bond generates a silicon electrophile that forms a Si-N bond prior to the N-H deprotonation by an intermediate Ru-H complex, only releasing H(2).
C David F Königs; Maria F Müller; Nuria Aiguabella; Hendrik F T Klare; Martin Oestreich
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  49     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-01-24     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  1506-8     Citation Subset:  IM    
Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 115, D-10623 Berlin, Germany.
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