Document Detail


Catalytic asymmetric synthesis of mycocerosic acid.
MedLine Citation:
PMID:  17252104     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The first catalytic asymmetric total synthesis of mycocerosic acid was achieved via the application of iterative enantioselective 1,4-addition reactions and allows for the efficient construction of 1,3-polymethyl arrays with full stereocontrol; further exemplified by the synthesis of tetramethyl-decanoic acid, a component of the preen-gland wax of the graylag goose, Anser anser.
Authors:
Bjorn ter Horst; Ben L Feringa; Adriaan J Minnaard
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2006-11-06
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1359-7345     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2007 Feb 
Date Detail:
Created Date:  2007-01-25     Completed Date:  2007-04-20     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  489-91     Citation Subset:  IM    
Affiliation:
Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
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MeSH Terms
Descriptor/Qualifier:
Catalysis
Chemistry, Organic / methods*
Fatty Acids / chemical synthesis*
Chemical
Reg. No./Substance:
0/Fatty Acids; 5691-98-5/mycocerosic acid

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