| Catalytic Selective Oxyamidation of Cyclic Enamides using Nitrenes. | |
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MedLine Citation:
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PMID: 22162185 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Yes, nitrenes did "N,O"! Intermolecular addition of nitrene to enecarbamates and enesulfonamides gives oxyamidated products in excellent yields of up to 98 % and with good levels of stereoselectivity. Complete regioselectivity is also observed, leading to the formation of N,O-acetals which can further react with various nucleophiles under acidic conditions (see scheme; TcesNH(2) =trichloroethylsulfamate). |
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Authors:
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Nicolas Gigant; Geoffroy Dequirez; Pascal Retailleau; Isabelle Gillaizeau; Philippe Dauban |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-12-8 |
Journal Detail:
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Title: Chemistry (Weinheim an der Bergstrasse, Germany) Volume: - ISSN: 1521-3765 ISO Abbreviation: - Publication Date: 2011 Dec |
Date Detail:
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Created Date: 2011-12-13 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9513783 Medline TA: Chemistry Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Institut de Chimie Organique et Analytiqe, UMR6005 CNRS, Université d'Orléans, 45067 Orléans Cedex 2 (France), Fax: (+33) 2 3841 7281. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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