| Catalytic Enantioselective Synthesis of Alkenylhydrosilane. | |
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MedLine Citation:
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PMID: 23136024 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety. |
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Authors:
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Kazunobu Igawa; Daisuke Yoshihiro; Nobumasa Ichikawa; Naoto Kokan; Katsuhiko Tomooka |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-11-7 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Nov |
Date Detail:
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Created Date: 2012-11-8 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan) http://www.cm.kyushu-u.ac.jp/tomooka. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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