| Catalytic Enantioselective Cyclization and C3-Fluorination of Polyprenoids. | |
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MedLine Citation:
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PMID: 23282101 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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(xylyl-phanephos)Pt2+ in combination with XeF2 mediates the consecutive diastereoselective cation-olefin cycliza-tion/fluorination of polyene substrates. Isolated yields were typically in the 60s while enantioselectivies reached as high as 87%. The data are consistent with a stereoretentive fluorina-tion of an intermediate P2Pt-alkyl cation intermediate. |
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Authors:
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Nikki A Cochrane; Ha H Nguyen; Michel R Gagné |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-2 |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: - ISSN: 1520-5126 ISO Abbreviation: J. Am. Chem. Soc. Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-3 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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