Document Detail


Catalytic asymmetric protonation of alpha-amino acid-derived ketene disilyl acetals using P-spiro diaminodioxaphosphonium barfates as chiral proton.
MedLine Citation:
PMID:  20715780     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Chiral diaminodioxaphosphonium salts have been developed and their unique abilities as a chiral proton have been revealed through the establishment of a highly enantioselective protonation of alpha-amino acid-derived ketene disilyl acetals.
Authors:
Daisuke Uraguchi; Natsuko Kinoshita; Takashi Ooi
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  132     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2010 Sep 
Date Detail:
Created Date:  2010-09-02     Completed Date:  2010-12-23     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  United States    
Other Details:
Languages:  eng     Pagination:  12240-2     Citation Subset:  IM    
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan.
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MeSH Terms
Descriptor/Qualifier:
Acetals / chemistry*
Amino Acids / chemistry*
Catalysis
Crystallography, X-Ray
Esters / chemical synthesis*,  chemistry
Models, Molecular
Molecular Structure
Organophosphorus Compounds / chemical synthesis,  chemistry*
Protons*
Silanes / chemistry*
Chemical
Reg. No./Substance:
0/Acetals; 0/Amino Acids; 0/Esters; 0/Organophosphorus Compounds; 0/Protons; 0/Silanes

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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