| Catalytic asymmetric aza-Darzens reaction with a vaulted biphenanthrol magnesium phosphate salt. | |
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MedLine Citation:
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PMID: 21476598 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Conditions for a catalytic asymmetric aza-Darzens aziridine synthesis mediated by a vaulted biphenanthrol (VAPOL) magnesium phosphate salt is described. Using simple substrates, this methodology explores the scope and reactivity of a new magnesium catalyst for an aziridination reaction capable of building chirality and complexity simultaneously. |
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Authors:
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Shawn E Larson; Guilong Li; Gerald B Rowland; Denise Junge; Rongcai Huang; H Lee Woodcock; Jon C Antilla |
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Publication Detail:
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Type: Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S. Date: 2011-04-05 |
Journal Detail:
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Title: Organic letters Volume: 13 ISSN: 1523-7052 ISO Abbreviation: Org. Lett. Publication Date: 2011 May |
Date Detail:
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Created Date: 2011-04-29 Completed Date: 2011-07-29 Revised Date: 2013-05-24 |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: United States |
Other Details:
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Languages: eng Pagination: 2188-91 Citation Subset: IM |
Affiliation:
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Department of Chemistry, University of South Florida, 4202 East Fowler Avenue CHE205A, Tampa, Florida 33620, United States. |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Aza Compounds
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chemistry* Catalysis Magnesium Compounds / chemistry* Molecular Structure Organophosphates / chemistry* Phenanthrenes / chemistry* Phosphates / chemistry* Stereoisomerism |
| Grant Support | |
ID/Acronym/Agency:
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1K22HL088341-01A1/HL/NHLBI NIH HHS; GM-082935/GM/NIGMS NIH HHS; K22 HL088341/HL/NHLBI NIH HHS; R01 GM082935/GM/NIGMS NIH HHS; R01 GM082935-01A1/GM/NIGMS NIH HHS; R01 GM082935-02/GM/NIGMS NIH HHS; R01 GM082935-03/GM/NIGMS NIH HHS; R01 GM082935-04/GM/NIGMS NIH HHS |
| Chemical | |
Reg. No./Substance:
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0/Aza Compounds; 0/Magnesium Compounds; 0/Organophosphates; 0/Phenanthrenes; 0/Phosphates; 0/biphenanthrol magnesium phosphate; 10043-83-1/magnesium phosphate |
| Comments/Corrections | |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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