Document Detail


Carbon nanoparticles from corn stalk soot and its novel application as stationary phase of hydrophilic interaction chromatography and per aqueous liquid chromatography.
MedLine Citation:
PMID:  22541020     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
Carbon nanoparticles (CNPs) (6-18nm in size) were prepared by refluxing corn stalk soot in nitric acid. The obtained acid-oxidized CNPs are soluble in water due to the existence of carboxylic and hydroxyl groups. (13)C NMR measurement shows the CNPs are mainly of sp(2) and sp(3) carbon structure different from CNPs obtained from candle soot and natural gas soot. Furthermore, these CNPs exhibit unique photoluminescence properties. Interestingly, the CNPs might be exploited to immobilize on the surface of porous silica particles as chromatographic stationary phase. The resultant packing material was evaluated by high-performance liquid chromatography, indicating that the new stationary phase could be used in hydrophilic interaction liquid chromatography (HILIC) and per aqueous liquid chromatography (PALC) modes. The separation of five nucleosides, four sulfa compounds and safflower injection was achieved by using the new column in the HILIC and PALC modes, respectively.
Authors:
Yuanyuan Li; Luan Xu; Tong Chen; Xiaoyan Liu; Zhigang Xu; Haixia Zhang
Publication Detail:
Type:  Journal Article     Date:  2012-03-29
Journal Detail:
Title:  Analytica chimica acta     Volume:  726     ISSN:  1873-4324     ISO Abbreviation:  Anal. Chim. Acta     Publication Date:  2012 May 
Date Detail:
Created Date:  2012-04-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370534     Medline TA:  Anal Chim Acta     Country:  Netherlands    
Other Details:
Languages:  eng     Pagination:  102-8     Citation Subset:  IM    
Copyright Information:
Copyright © 2012 Elsevier B.V. All rights reserved.
Affiliation:
Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Lanzhou University, Lanzhou 730000, China; Key Laboratory of Energy and Chemical Engineering, Ningxia University, Yinchuan 750021, China.
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