Document Detail


Carbon Disulfide Assisted Polymerization of Benzene.
MedLine Citation:
PMID:  22309055     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The chemical transformation of benzene (C6H6) and carbon disulfide (CS2) binary solution under high pressure condition is investigated by means of Raman spectroscopy up to 6.8 GPa. On increasing the pressure, all the Raman bands of benzene decrease in intensity, whereas new broad bands start to be observed at 1520 and 1450 cm-1, indicating a highly cross-linked polymer is formed. The recovered sample is analyzed through Raman and FT-IR spectroscopy and is identified as a saturated hydrocarbons and element sulfur.
Authors:
Mi Zhou; Zhan Long Li; Zhiwei Men; Shu-Qin Gao; Zuo Wei Li; Guohui Lu; Chenglin Sun
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-2-6
Journal Detail:
Title:  The journal of physical chemistry. B     Volume:  -     ISSN:  1520-5207     ISO Abbreviation:  -     Publication Date:  2012 Feb 
Date Detail:
Created Date:  2012-2-7     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101157530     Medline TA:  J Phys Chem B     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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