| Carbometalations of simple alkenes with allyldibromoborane. | |
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MedLine Citation:
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PMID: 10822588 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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[formula: see text] The allylboration of alkenes with allyldibromoborane is described. Utilizing an improved methodology for the synthesis of allyldibromoborane, 1,3-dienes, styrene, and even isolated alkenes could be carbometalated in high yield regio- and stereospecifically at 0 degree C. This high reactivity of allyldibromoborane significantly expands the scope of carbometalations of alkenes. |
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Authors:
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D E Frantz; D A Singleton |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, P.H.S. |
Journal Detail:
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Title: Organic letters Volume: 1 ISSN: 1523-7060 ISO Abbreviation: Org. Lett. Publication Date: 1999 Aug |
Date Detail:
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Created Date: 2000-07-06 Completed Date: 2000-07-06 Revised Date: 2007-11-14 |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: UNITED STATES |
Other Details:
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Languages: eng Pagination: 485-6 Citation Subset: IM |
Affiliation:
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Department of Chemistry, Texas A&M University, College Station 77843, USA. |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Alkenes
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chemistry* Boron Compounds / chemistry* Stereoisomerism |
| Grant Support | |
ID/Acronym/Agency:
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GM-45617/GM/NIGMS NIH HHS |
| Chemical | |
Reg. No./Substance:
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0/Alkenes; 0/Boron Compounds; 0/allyldibromoborane |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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