Document Detail

Capturing C(84) Isomers as Chlorides and Pentafluoroethyl Derivatives: C(84)Cl(22) and C(84)(C(2)F(5))(12).
MedLine Citation:
PMID:  22335610     Owner:  NLM     Status:  Publisher    
A mixture of higher fullerenes C(76)-C(96) was pentafluoroethylated with C(2)F(5)I at 250 °C affording a mixture of C(2)F(5) derivatives. After separation with high-performance liquid chromatography, the second C(2)F(5) derivative of C(84)(16), C(84)(C(2)F(5))(12), was investigated by X-ray crystallography and compared with the known isomer in terms of addition patterns and formation energies. Chlorination of a C(84) isomeric mixture with VCl(4) at 350-400 °C resulted in the formation of C(84)Cl(22). X-ray diffraction study revealed the superposition of several C(84)Cl(22) molecules with different isomeric C(84) cages but the same chlorination pattern.
Maria A Lanskikh; Nadezhda B Tamm; Lev N Sidorov; Sergey I Troyanov
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-2-15
Journal Detail:
Title:  Inorganic chemistry     Volume:  -     ISSN:  1520-510X     ISO Abbreviation:  -     Publication Date:  2012 Feb 
Date Detail:
Created Date:  2012-2-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0366543     Medline TA:  Inorg Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Chemistry Department, Moscow State University , Leninskie Gory, 119991 Moscow, Russia.
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