Document Detail


Calcium-dependent incorporation of choline into phosphatidylcholine (PC) by base-exchange in rat brain membranes occurs preferentially with phospholipid substrates containing docosahexaenoic acid (22:6(n-3)).
MedLine Citation:
PMID:  2171666     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The fatty acid composition of phosphatidylcholine (PC) formed by base-exchange was examined in rat brain membranes in vitro. The free choline incorporated into subspecies of PC by this phospholipase-D type activity can be distinguished from that which might enter indirectly via the last enzyme of the de novo pathway for phospholipid biosynthesis, cholinephosphotransferase, by its ionic requirements. Choline base-exchange in lysed synaptosomes is optimal when assayed at extracellular (mM) calcium concentrations and is blocked by magnesium. As much as 40% of the choline incorporated by base-exchange into rat brain membranes was recovered in subspecies of PC, representing no more than 10% of the total PC pool, which contained docosahexaenoic acid (22:6(n-3)). Docosahexaenoic acid is enriched in electrically-excitable membranes and its content in phospholipids of rat and human brain change during early development and increase with age.
Authors:
P G Holbrook; R J Wurtman
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Publication Detail:
Type:  Journal Article; Research Support, U.S. Gov't, P.H.S.    
Journal Detail:
Title:  Biochimica et biophysica acta     Volume:  1046     ISSN:  0006-3002     ISO Abbreviation:  Biochim. Biophys. Acta     Publication Date:  1990 Sep 
Date Detail:
Created Date:  1990-12-04     Completed Date:  1990-12-04     Revised Date:  2007-11-14    
Medline Journal Info:
Nlm Unique ID:  0217513     Medline TA:  Biochim Biophys Acta     Country:  NETHERLANDS    
Other Details:
Languages:  eng     Pagination:  185-8     Citation Subset:  IM    
Affiliation:
Department of Brain and Cognitive Sciences E25-604, Massachusetts Institute of Technology, Cambridge.
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MeSH Terms
Descriptor/Qualifier:
Animals
Brain / drug effects,  metabolism*
Brain Chemistry
Calcium / pharmacology*
Cell Membrane / metabolism
Choline / metabolism*
Diacylglycerol Cholinephosphotransferase / metabolism
Docosahexaenoic Acids / analysis*,  metabolism
Magnesium / pharmacology
Male
Phosphatidylcholines / metabolism*
Phospholipase D / metabolism
Phospholipids / analysis
Rats
Rats, Inbred Strains
Synaptosomes / drug effects,  metabolism
Grant Support
ID/Acronym/Agency:
1 F31 MH09199-01/MH/NIMH NIH HHS
Chemical
Reg. No./Substance:
0/Phosphatidylcholines; 0/Phospholipids; 25167-62-8/Docosahexaenoic Acids; 62-49-7/Choline; 7439-95-4/Magnesium; 7440-70-2/Calcium; EC 2.7.8.2/Diacylglycerol Cholinephosphotransferase; EC 3.1.4.4/Phospholipase D

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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