| C2-Symmetric Cyclic Selenium Catalyzed Enantioselective Bromoaminocyclization. | |
| | |
MedLine Citation:
|
PMID: 23312005 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
|
A catalytic asymmetric bromocyclization of tri-substituted olefinic amides is reported using a C2-symmetric mannitol-derived cyclic selenium catalyst and stoichiometric amount of N-bromophthalimide. The resulting enantioenriched pyrrolidine products, which contain two stereogenic centers, could undergo rearrangement to yield 2,3-disubstituted piperidine in excellent diastereoselectivity and enantiospecificity. |
| | |
Authors:
|
Feng Chen; Chong Kiat Tan; Ying-Yeung Yeung |
Related Documents
:
|
3803565 - Antihypertensive activity of arylidenaminoguanidine derivatives. 19445965 - Antiviral activity of indole derivatives. 20188575 - Sar and molecular mechanism study of novel acylhydrazone compounds targeting hiv-1 ca. 15755655 - Structural modification of phenylpropanoid-derived compounds and the effects on their p... 14961685 - Controllable enantioselective friedel-crafts reaction between indoles and alkylidene ma... 10525295 - Consecutive halogen transfer between various functional groups induced by reaction of h... |
Publication Detail:
|
Type: JOURNAL ARTICLE Date: 2013-1-13 |
Journal Detail:
|
Title: Journal of the American Chemical Society Volume: - ISSN: 1520-5126 ISO Abbreviation: J. Am. Chem. Soc. Publication Date: 2013 Jan |
Date Detail:
|
Created Date: 2013-1-14 Completed Date: - Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: - |
Other Details:
|
Languages: ENG Pagination: - Citation Subset: - |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
|
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Identification of Missing Proteins in the neXtProt Database and Unregistered Phosphopeptides in the ...
Next Document: Serum nitric oxide level could be a predictive biomarker for detection of critical ischaemia duratio...