Document Detail

C-Difluoromethylene-containing, C-trifluoromethyl and C-perfluoroalkyl carbohydrates. Synthesis by carbohydrate transformation or building block methods.
MedLine Citation:
PMID:  10968679     Owner:  NLM     Status:  MEDLINE    
The synthetic methods for preparing carbohydrates bearing a C-branched substituent of the type CF2-Y, with Y = F, Y = CnF(2n + 1) or Y = a carbon-attached or heteroatom-attached nonfluorinated residues, are reviewed. Both direct introduction of C-branched fluorinated substituents (direct trifluoromethylation, perfluoroalkylation or difluoromethylenation) and building block methods from fluorinated synthons are considered.
R Plantier-Royon; C Portella
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't; Review    
Journal Detail:
Title:  Carbohydrate research     Volume:  327     ISSN:  0008-6215     ISO Abbreviation:  Carbohydr. Res.     Publication Date:  2000 Jul 
Date Detail:
Created Date:  2000-12-04     Completed Date:  2001-01-11     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  0043535     Medline TA:  Carbohydr Res     Country:  NETHERLANDS    
Other Details:
Languages:  eng     Pagination:  119-46     Citation Subset:  IM    
Laboratoire Réactions Sélectives et Applications, Associé au CNRS (UMR 6519), Université de Reims, Facult des Sciences, France.
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MeSH Terms
Carbohydrates / chemical synthesis,  chemistry*
Fluorine / chemistry*
Fluorocarbons / chemical synthesis,  chemistry*
Molecular Structure
Reg. No./Substance:
0/Carbohydrates; 0/Fluorocarbons; 7782-41-4/Fluorine

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