Document Detail


Brittle and ductile adjustable cement derived from calcium phosphate cement/polyacrylic acid composites.
MedLine Citation:
PMID:  18502499     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
OBJECTIVES: Bone filler has been used over the years in dental and biomedical applications. The present work is to characterize a non-dispersive, fast setting, modulus adjustable, high bioresorbable composite bone cement derived from calcium phosphate-based cement combined with polymer and binding agents. This cement, we hope, will not swell in simulated body fluid and keep the osteogenetic properties of the dry bone and avoid its disadvantages of being brittle. METHODS: We developed a calcium phosphate cement (CPC) of tetracalcium phosphate/dicalcium phosphate anhydrous (TTCP/DCPA)-polyacrylic acid with tartaric acid, calcium fluoride additives and phosphate hardening solution. RESULTS: The results show that while composite, the hard-brittle properties of 25wt% polyacrylic acid are proportional to CPC and mixing with additives is the same as those of the CPC without polyacrylic acid added. With an increase of polyacrylic acid/CPC ratio, the 67wt% samples revealed ductile-tough properties and 100wt% samples kept ductile or elastic properties after 24h of immersion. The modulus range of this development was from 200 to 2600MPa after getting immersed in simulated body fluid for 24h. SIGNIFICANCE: The TTCP/DCPA-polyacrylic acid based CPC demonstrates adjustable brittle/ductile strength during setting and after immersion, and the final reaction products consist of high bioresorbable monetite/brushite/calcium fluoride composite with polyacrylic acid.
Authors:
Wen-Cheng Chen; Chien-Ping Ju; Jen-Chyan Wang; Chun-Cheng Hung; Jiin-Huey Chern Lin
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2008-05-27
Journal Detail:
Title:  Dental materials : official publication of the Academy of Dental Materials     Volume:  24     ISSN:  0109-5641     ISO Abbreviation:  Dent Mater     Publication Date:  2008 Dec 
Date Detail:
Created Date:  2008-10-28     Completed Date:  2009-01-23     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  8508040     Medline TA:  Dent Mater     Country:  England    
Other Details:
Languages:  eng     Pagination:  1616-22     Citation Subset:  D    
Affiliation:
Faculty of Dentistry, Kaohsiung Medical University, 807 Kaohsiung, Taiwan. chenwc@kmu.edu.tw
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MeSH Terms
Descriptor/Qualifier:
Absorbable Implants
Acrylic Resins / chemistry*
Bone Cements / chemical synthesis*
Calcium Fluoride / chemistry
Calcium Phosphates / chemistry*
Dental Stress Analysis
Elastic Modulus
Hardness
Materials Testing
Phase Transition
Tartrates / chemistry
Tensile Strength
Water
Chemical
Reg. No./Substance:
0/Acrylic Resins; 0/Bone Cements; 0/Calcium Phosphates; 0/Tartrates; 0/tetracalcium phosphate; 526-83-0/tartaric acid; 7732-18-5/Water; 7757-93-9/dicalcium phosphate anhydrous; 7789-75-5/Calcium Fluoride

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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