| Blueshifting the Onset of Optical UV Absorption for Water under Pressure. | |
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MedLine Citation:
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PMID: 21635126 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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First-principles calculations show that the optical UV absorption onset of solid water is blueshifted with increasing pressure. Across several crystal structures and a wide pressure range, the optical gap increases almost linearly with external pressure, making solid water more transparent. The origin of this unusual effect can be traced back to an increased Stark shift caused by water's electrostatic environment at smaller volumes. |
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Authors:
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Andreas Hermann; Peter Schwerdtfeger |
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Publication Detail:
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Type: Journal Article Date: 2011-05-06 |
Journal Detail:
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Title: Physical review letters Volume: 106 ISSN: 1079-7114 ISO Abbreviation: Phys. Rev. Lett. Publication Date: 2011 May |
Date Detail:
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Created Date: 2011-06-03 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0401141 Medline TA: Phys Rev Lett Country: United States |
Other Details:
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Languages: eng Pagination: 187403 Citation Subset: IM |
Affiliation:
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Department of Chemistry, The University of Auckland, Private Bag 92019, Auckland, New Zealand and MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University Wellington, New Zealand. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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