| Bis-morpholine-substituted perylene bisimides: impact of isomeric arrangement on electrochemical and spectroelectrochemical properties. | |
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MedLine Citation:
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PMID: 18855454 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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The synthesis and separation of the 1,6- and 1,7- isomers of N,N'-bis(n-butyl)dimorpholino-3,4:9,10-perylenetetracarboxylic acid bisimide are reported. Investigations of the electrochemical and spectroscopic, in particular, spectroelectrochemical, properties of the two isomers reveal a sequence of electrochemically and chemically reversible redox processes for both isomers. Importantly, the 1,7-isomer of N,N'-bis(n-butyl)dimorpholino-3,4:9,10-perylenetetracarboxylic acid bisimide was observed to undergo a two-electron oxidation process, which contrasts with the behavior of both the corresponding 1,6-isomer and other related amino-substituted perylene bis-imide species. |
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Authors:
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Gudrun Goretzki; E Stephen Davies; Stephen P Argent; Wassim Z Alsindi; Alexander J Blake; John E Warren; Jonathan McMaster; Neil R Champness |
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Publication Detail:
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Type: Journal Article Date: 2008-10-15 |
Journal Detail:
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Title: The Journal of organic chemistry Volume: 73 ISSN: 1520-6904 ISO Abbreviation: J. Org. Chem. Publication Date: 2008 Nov |
Date Detail:
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Created Date: 2008-11-14 Completed Date: 2009-01-09 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: United States |
Other Details:
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Languages: eng Pagination: 8808-14 Citation Subset: - |
Affiliation:
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School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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