Document Detail

Bis{μ-4,4'-dibromo-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}bis-[chloridomanganese(III)] N,N-dimethyl-formamide disolvate.
MedLine Citation:
PMID:  21579688     Owner:  NLM     Status:  PubMed-not-MEDLINE    
The asymmetric unit of the title compound, [Mn(2)(C(20)H(12)Br(2)N(2)O(2))(2)Cl(2)]·2C(3)H(7)NO, contains one half of a centrosymmetric dinuclear Mn(III) complex and an N,N-dimethyl-formamide solvent mol-ecule. In the complex, the two Mn(III) ions are bridged by two O atoms from two symmetry-related N,N'-bis-(5-bromo-salicyl-idene)-1,2-diimino-benzene dianionic ligands with the longer Mn-O distance of 2.703 (3) Å, thus each Mn ion is six-coordinated by two N and three O atoms from the two dianionic ligands and one capping Cl atom in a distorted octa-hedral environment. The crystal structure displays inter-molecular π-π inter-actions between adjacent benzene rings, with a shortest centroid-centroid distance of 3.673 (2) Å, and inter-molecular C-H⋯O, C-H⋯ Cl and C-H⋯ Br hydrogen bonds.
Kwang Ha
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Publication Detail:
Type:  Journal Article     Date:  2010-01-30
Journal Detail:
Title:  Acta crystallographica. Section E, Structure reports online     Volume:  66     ISSN:  1600-5368     ISO Abbreviation:  Acta Crystallogr E Struct Rep Online     Publication Date:  2010  
Date Detail:
Created Date:  2011-05-17     Completed Date:  2011-07-14     Revised Date:  2011-11-11    
Medline Journal Info:
Nlm Unique ID:  101089178     Medline TA:  Acta Crystallogr E Struct Rep Online     Country:  England    
Other Details:
Languages:  eng     Pagination:  m233-4     Citation Subset:  -    
School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.
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