Document Detail


Bioavailability of the organophosphorous insecticide chlorpyrifos to the suspension-feeding bivalve, Mercenaria mercenaria, following exposure to dissolved and particulate matter.
MedLine Citation:
PMID:  12959537     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Under estuarine conditions, hydrophobic pesticides undergo physical/chemical partitioning into dissolved and particulate fractions of sediments. Our experimental study using 14C-chlorpyrifos (14C-CHPY) showed that sorptive associations of this common insecticide with particulate (>0.2 microm) and dissolved fractions (<0.2 microm) of sediments strongly influenced uptake, tissue absorption, and elimination in the estuarine bivalve Mercenaria mercenaria. Bivalves were fed algae mixed with particulate and dissolved fractions of 14C-CHPY-contaminated estuarine sediment particles, components of estuarine sediments (silica, humic acids), and a naturally occurring food source (phytoplankton) to quantify relative uptake, tissue absorption efficiencies, and elimination of 14C-CHPY. Measurements of 14C-CHPY tissue absorption efficiencies (AE%) indicated that particle source qualities influenced much of the insecticide bioavailability. Mean tissue AE% of 14C-CHPY associated with different particulate fractions ranged from 23 to 31%, while uptake from the dissolved/colloidal forms resulted in low (7-17%) AE%. Our data indicated that 14C-CHPY is more likely to bioaccumulate through ingestion of contaminated particulate material than through filtration/ingestion of dissolved/colloidal material. The high selectivity and digestibility of algae particles by M. mercenaria, a potentially ingested food source, may play an important role in the bioavailability of chlorpyrifos in this animal.
Authors:
Adriana C Bejarano; Anneli Widenfalk; Alan W Decho; G Thomas Chandler
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Publication Detail:
Type:  Journal Article; Research Support, U.S. Gov't, Non-P.H.S.    
Journal Detail:
Title:  Environmental toxicology and chemistry / SETAC     Volume:  22     ISSN:  0730-7268     ISO Abbreviation:  Environ. Toxicol. Chem.     Publication Date:  2003 Sep 
Date Detail:
Created Date:  2003-09-08     Completed Date:  2003-12-09     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  8308958     Medline TA:  Environ Toxicol Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  2100-5     Citation Subset:  IM    
Affiliation:
Department of Environmental Health Sciences, University of South Carolina, Columbia, South Carolina 29208, USA. acbejara@mailbox.sc.edu
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MeSH Terms
Descriptor/Qualifier:
Algae / chemistry
Animals
Biological Availability
Bivalvia / physiology*
Carbon Radioisotopes / pharmacokinetics
Chlorpyrifos / pharmacokinetics*,  toxicity
Feeding Behavior
Geologic Sediments / chemistry*
Insecticides / pharmacokinetics*,  toxicity
Particle Size
Tissue Distribution
Chemical
Reg. No./Substance:
0/Carbon Radioisotopes; 0/Insecticides; 2921-88-2/Chlorpyrifos

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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