| Bicyclic guanidinium tetraphenylborate: a photobase generator and a photocatalyst for living anionic ring-opening polymerization and cross-linking of polymeric materials containing ester and hydroxy groups. | |
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MedLine Citation:
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PMID: 18528981 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) with pKa of 26.03 in acetonitrile can be effectively released by photolysis of TBD.HBPh4 salt, which represents a new family of short-wave UV photobase generators. This photobase generator enables the photoinduced living ring-opening polymerization of cyclic esters and the photoinduced cross-linking of various polymeric materials containing the hydroxyl-ester groups. |
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Authors:
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Xun Sun; Jian Ping Gao; Zhi Yuan Wang |
Publication Detail:
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Type: Journal Article Date: 2008-06-04 |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: 130 ISSN: 1520-5126 ISO Abbreviation: J. Am. Chem. Soc. Publication Date: 2008 Jul |
Date Detail:
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Created Date: 2008-06-26 Completed Date: 2008-07-31 Revised Date: 2008-12-22 |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: United States |
Other Details:
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Languages: eng Pagination: 8130-1 Citation Subset: - |
Affiliation:
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Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario, Canada K1S 5B6. |
Export Citation:
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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