| Biaryl synthesis with control of axial chirality. | |
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MedLine Citation:
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PMID: 17036104 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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Biaryls have been a persistent focus of interest for chemists since it was recognised, more than 80 years ago, that they can manifest the axial chirality that is inherent in structures consisting of intersecting dissymmetric planes. In recent decades their importance has risen steeply as this structural motif proved spectacularly successful in catalytic synthetic roles and was found to be significant in the context of biological activity. As a consequence, synthetic methods which allowed the construction of biaryls with axial stereocontrol have become highly desirable, and this article traces the development of non-resolution approaches to biaryls with a chosen axial configuration. |
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Authors:
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Timothy W Wallace |
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Publication Detail:
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Type: Journal Article Date: 2006-08-01 |
Journal Detail:
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Title: Organic & biomolecular chemistry Volume: 4 ISSN: 1477-0520 ISO Abbreviation: Org. Biomol. Chem. Publication Date: 2006 Sep |
Date Detail:
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Created Date: 2006-10-12 Completed Date: 2007-09-28 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101154995 Medline TA: Org Biomol Chem Country: England |
Other Details:
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Languages: eng Pagination: 3197-210 Citation Subset: - |
Affiliation:
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School of Chemistry, University of Manchester, Oxford Road, Manchester, UKM13 9PL. tim.wallace@manchester.ac.uk |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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