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Asymmetric zinc-catalyzed hydrosilylation of ketones and the effect of carboxylate on the enantioselectivity.
MedLine Citation:
PMID:  23620263     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
Several chiral ligands containing (R,R)-diaminocyclohexane moieties and pyrrole, furan, or benzene have been synthesized. These ligands were tested in enantioselective zinc-catalyzed hydrosilylation reactions; excellent enantioselectivities were obtained when the ligands containing (R,R)-diaminocyclohexane moieties and furan rings were used. For comparison, zinc chloride combined with different potassium carboxylate salts and ligands were also tested for catalytic hydrosilylation reactions. Chirality 25:275-280, 2013. © 2013 Wiley Periodicals, Inc.
Authors:
Shaofeng Pang; Jiajian Peng; Jiayun Li; Ying Bai; Wenjun Xiao; Guoqiao Lai
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Chirality     Volume:  25     ISSN:  1520-636X     ISO Abbreviation:  Chirality     Publication Date:  2013 May 
Date Detail:
Created Date:  2013-04-26     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  8914261     Medline TA:  Chirality     Country:  United States    
Other Details:
Languages:  eng     Pagination:  275-80     Citation Subset:  IM    
Copyright Information:
Copyright © 2013 Wiley Periodicals, Inc.
Affiliation:
Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou, 310012, China.
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