| Asymmetric counteranion-directed catalysis: concept, definition, and applications. | |
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MedLine Citation:
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PMID: 23280677 Owner: NLM Status: In-Data-Review |
Abstract/OtherAbstract:
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Recently, the use of enantiomerically pure counteranions for the induction of asymmetry in reactions proceeding through cationic intermediates has emerged as an exciting new concept, which has been termed asymmetric counteranion-directed catalysis (ACDC). Despite its success, the concept has not been fully defined and systematically discussed to date. This Review closes this gap by providing a clear definition of ACDC and by examining both clear cases as well as more ambiguous examples to illustrate the differences and overlaps with other catalysis concepts. |
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Authors:
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Manuel Mahlau; Benjamin List |
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Publication Detail:
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Type: Journal Article Date: 2012-11-28 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: 52 ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-01-02 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: Germany |
Other Details:
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Languages: eng Pagination: 518-33 Citation Subset: IM |
Copyright Information:
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Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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