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Asymmetric binary acid catalysis: chiral phosphoric acid as dual ligand and acid.
MedLine Citation:
PMID:  23150877     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Recently, chiral Brønsted acids as dual ligand and acid catalysts in the context of metal catalysis have been developed. Such binary catalytic systems synergistically integrate chiral Brønsted acids and metal catalysts as a result of their weakly coordinating behaviors. The resulting binary acid catalysts have enabled effective reactions of a range of olefins/aromatics, beyond the scope of typical acid catalysis. Our endeavors in developing asymmetric binary acid catalysis are summarized in this feature article.
Authors:
Jian Lv; Sanzhong Luo
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-14
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key of Molecular Recognition and Function Institute of Chemistry, Chinese Academy of Sciences, China. luosz@iccas.ac.cn.
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