Document Detail


Asymmetric synthesis of cyclic cis-beta-amino acid derivatives using sulfinimines and prochiral Weinreb amide enolates.
MedLine Citation:
PMID:  20462208     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Cyclic cis-beta-amino Weinreb amides, valuable building blocks for the asymmetric synthesis of cyclic beta-amino acids derivatives, are readily prepared via ring-closing metathesis of sulfinimine-derived N-sulfinyl beta-amino diene Weinreb amides. These unsaturated cyclic cis-beta-amino Weinreb amides are valuable building blocks for the asymmetric synthesis of cyclic beta-amino acid derivatives.
Authors:
Franklin A Davis; Naresh Theddu
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Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural    
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  75     ISSN:  1520-6904     ISO Abbreviation:  J. Org. Chem.     Publication Date:  2010 Jun 
Date Detail:
Created Date:  2010-05-28     Completed Date:  2010-09-03     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  3814-20     Citation Subset:  IM    
Affiliation:
Department of Chemistry, Temple University, Philadelphia, Pennsylvania 19122, USA. fdavis@temple.edu
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MeSH Terms
Descriptor/Qualifier:
Amides / chemistry
Amino Acids / chemical synthesis*,  chemistry
Cyclization
Imines / chemistry*
Sulfonium Compounds / chemistry*
Grant Support
ID/Acronym/Agency:
GM57870/GM/NIGMS NIH HHS
Chemical
Reg. No./Substance:
0/Amides; 0/Amino Acids; 0/Imines; 0/Sulfonium Compounds; 0/sulfinimine

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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