Document Detail


Aspects of the atmospheric chemistry of amides.
MedLine Citation:
PMID:  20737533     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
The gas-phase reactions of six amides, formamide, N-methyl formamide, N,N-dimethyl formamide, acetamide, N-methyl acetamide and N,N-dimethyl acetamide with the atmospheric oxidants OH radicals and Cl atoms, but in a number of cases also with NO(3) radicals and ozone, are presented and discussed. Kinetic and mechanistic information available from previous experimental work is combined with new kinetic and product information from this study, obtained in a photoreactor using in situ FTIR spectrometry, to elucidate the gas-phase photooxidation mechanisms of the amides and assess potential environmental implications.
Authors:
Ian Barnes; Geraldine Solignac; Abdelwahid Mellouki; Karl H Becker
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Chemphyschem : a European journal of chemical physics and physical chemistry     Volume:  11     ISSN:  1439-7641     ISO Abbreviation:  Chemphyschem     Publication Date:  2010 Dec 
Date Detail:
Created Date:  2010-12-14     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100954211     Medline TA:  Chemphyschem     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  3844-57     Citation Subset:  IM    
Affiliation:
Fachbereich C-Physikalische Chemie, Bergische Universität Wuppertal, Gauss-Strasse 20, 42119 Wuppertal (Germany), Fax: (+44)  202 439 2505.
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