Document Detail


Aqueous extract of the pericarp of Sapindus trifoliatus fruits: a novel 'green' catalyst for the aldimine synthesis.
MedLine Citation:
PMID:  20658668     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
The catalytic efficiency in organic synthesis of the aqueous extract of the pericarp of Sapindus trifoliatus fruits was evaluated. The synthesis of a series of aldimines from aromatic aldehydes and amines was successfully catalyzed by the extract, whereas aromatic ketones and amines did not yield ketimines under comparable reaction conditions, indicating the chemoselective catalysis of the extract. The catalytic activity of the extract is due to saponins, which have a common structural skeleton containing a pentacyclic triterpenoid part substituted with different carbohydrate side chains. The mild conditions, high yields, and short reaction times not only make this protocol a valuable alternative to the conventional methods, but it also becomes significant under the roof of environmentally greener and safer processes.
Authors:
Santosh Pore; Gajanan Rashinkar; Kavita Mote; Rajeshri Salunkhe
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Chemistry & biodiversity     Volume:  7     ISSN:  1612-1880     ISO Abbreviation:  Chem. Biodivers.     Publication Date:  2010 Jul 
Date Detail:
Created Date:  2010-07-26     Completed Date:  2010-11-23     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101197449     Medline TA:  Chem Biodivers     Country:  Switzerland    
Other Details:
Languages:  eng     Pagination:  1796-800     Citation Subset:  IM    
Affiliation:
Department of Chemistry, Shivaji University, Kolhapur 416004, India.
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MeSH Terms
Descriptor/Qualifier:
Aldehydes / chemistry
Amines / chemistry
Catalysis
Fruit / chemistry
Imines / chemical synthesis*
Plant Extracts / chemistry*
Sapindus / chemistry*
Chemical
Reg. No./Substance:
0/Aldehydes; 0/Amines; 0/Imines; 0/Plant Extracts

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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