| Aqua-tricarbon-yl(3,5,7-tribromo-tropolonato)rhenium(I) methanol solvate. | |
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MedLine Citation:
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PMID: 21581205 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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The title complex, [Re(C(7)H(2)Br(3)O(2))(CO)(3)(H(2)O)]·CH(3)OH, crystallized as a neutral Re(I) compound and one methanol solvent mol-ecule in the asymmetric unit. The metal centre is coordinated facially by three carbonyl groups. The bidentate tribromo-tropolanate ligand and a water mol-ecule complete the distorted octahedral coordination around the central metal. Inter-molecular Br⋯O [3.226 (5) Å] and Br⋯Br [3.590 (2) Å] contacts are observed between adjacent mol-ecules. These contacts, together with an array of O-H⋯O, O-H⋯Br and C-H⋯O hydrogen bonds, complete a three-dimensional polymeric network formed between the methanol solvent and the complex. |
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Authors:
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Marietjie Schutte; Hendrik G Visser; Andreas Roodt |
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Publication Detail:
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Type: Journal Article Date: 2008-11-22 |
Journal Detail:
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Title: Acta crystallographica. Section E, Structure reports online Volume: 64 ISSN: 1600-5368 ISO Abbreviation: Acta Crystallogr E Struct Rep Online Publication Date: 2008 |
Date Detail:
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Created Date: 2011-05-17 Completed Date: 2011-07-14 Revised Date: 2011-11-11 |
Medline Journal Info:
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Nlm Unique ID: 101089178 Medline TA: Acta Crystallogr E Struct Rep Online Country: England |
Other Details:
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Languages: eng Pagination: m1610-1 Citation Subset: - |
Affiliation:
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Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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