Document Detail


Applications of microwave-assisted organic synthesis on the multigram scale.
MedLine Citation:
PMID:  16312146     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
This review presents a summary of reactions performed using microwave irradiation on a multigram scale. Results are described in the context of existing equipment, and equipment currently in development, for the processing of multigram to kilogram quantities of materials including single- and multimode microwave reactors and batch, batch-flow and continuous-flow systems. Although limited in number, reports found in the literature to date suggest that with appropriate controls, reproducible scale-up of microwave reactions is feasible and requires minimal re-optimization of laboratory-scale reaction conditions. This feature, along with the dramatic reductions in reaction time generally observed for microwave reactions suggests that application of this technology in process research could be beneficial.
Authors:
Scott E Wolkenberg; William D Shipe; Craig W Lindsley; James P Guare; Joseph M Pawluczyk
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Publication Detail:
Type:  Journal Article; Review    
Journal Detail:
Title:  Current opinion in drug discovery & development     Volume:  8     ISSN:  1367-6733     ISO Abbreviation:  Curr Opin Drug Discov Devel     Publication Date:  2005 Nov 
Date Detail:
Created Date:  2005-11-29     Completed Date:  2006-11-06     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100887519     Medline TA:  Curr Opin Drug Discov Devel     Country:  England    
Other Details:
Languages:  eng     Pagination:  701-8     Citation Subset:  IM    
Affiliation:
Merck & Co Inc, Technology Enabled Synthesis Group, PO Box 4, Sumneytown Pike, West Point, PA 19486, USA. scott_wolkenberg@merck.com
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MeSH Terms
Descriptor/Qualifier:
Benzopyrans / chemical synthesis
Combinatorial Chemistry Techniques
Dioxolanes / chemical synthesis
Microwaves*
Organic Chemicals / chemical synthesis*
Quinazolines / chemical synthesis
Temperature
Thiocarbamates / chemical synthesis
Time Factors
Chemical
Reg. No./Substance:
0/Benzopyrans; 0/Dioxolanes; 0/Organic Chemicals; 0/Quinazolines; 0/Thiocarbamates

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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