Document Detail


Application of natural citric acid sources and their role on arsenic removal from drinking water: A green chemistry approach.
MedLine Citation:
PMID:  23122734     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Solar Oxidation and Removal of Arsenic (SORAS) is a low-cost non-hazardous technique for the removal of arsenic (As) from groundwater. In this study, we tested the efficiency of natural citric acid sources extracted from tomato, lemon and lime to promote SORAS for As removal at the household level. The experiment was conducted in the laboratory using both synthetic solutions and natural groundwater samples collected from As-polluted areas in West Bengal. The role of As/Fe molar ratios and citrate doses on As removal efficiency were checked in synthetic samples. The results demonstrate that tomato juice (as citric acid) was more efficient to remove As from both synthetic (percentage of removal: 78-98%) and natural groundwater (90-97%) samples compared to lemon (61-83% and 79-85%, respectively) and lime (39-69% and 63-70%, respectively) juices. The As/Fe molar ratio and the citrate dose showed an 'optimized central tendency' on As removal. Anti-oxidants, e.g. 'hydroxycinnamates', found in tomato, were shown to have a higher capacity to catalyze SORAS photochemical reactions compared to 'flavanones' found in lemon or lime. The application of this method has several advantages, such as eco- and user- friendliness and affordability at the household level compared to other low-cost techniques.
Authors:
Santanu Majumder; Bibhash Nath; Simita Sarkar; Sk Mijanul Islam; Jochen Bundschuh; Debashis Chatterjee; Manuela Hidalgo
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-13
Journal Detail:
Title:  Journal of hazardous materials     Volume:  -     ISSN:  1873-3336     ISO Abbreviation:  J. Hazard. Mater.     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-11-5     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9422688     Medline TA:  J Hazard Mater     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 Elsevier B.V. All rights reserved.
Affiliation:
Department of Chemistry, University of Girona, Campus Montilivi s/n., 17071 Girona, Spain; Department of Chemistry, University of Kalyani, Kalyani 741 235, West Bengal, India. Electronic address: san_chem_03@yahoo.co.in.
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