| Application of Microflow Conditions to Visible Light Photoredox Catalysis. | |
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MedLine Citation:
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PMID: 22587670 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Applications of microflow conditions for visible light photoredox catalysis have successfully been developed. Operationally simple microreactor and FEP (fluorinated ethylene propylene copolymer) tube reactor systems enable significant improvement of several photoredox reactions using different photocatalysts such as [Ru(bpy)(3)](2+) and Eosin Y. Apart from rate acceleration, this approach facilitates previously challenging transformations of nonstabilized intermediates. Additionally, the productivity of the synergistic, catalytic enantioselective photoredox α-alkylation of aldehydes was demonstrated to be increased by 2 orders of magnitude. |
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Authors:
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Matthias Neumann; Kirsten Zeitler |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-5-15 |
Journal Detail:
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Title: Organic letters Volume: - ISSN: 1523-7052 ISO Abbreviation: - Publication Date: 2012 May |
Date Detail:
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Created Date: 2012-5-16 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Institut für Organische Chemie, Universität Regensburg , Universitätsstrasse 31, D-93053 Regensburg, Germany. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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