Document Detail


Amplified two-photon absorption in trans-a(2) b(2) -porphyrins bearing nitrophenylethynyl substituents.
MedLine Citation:
PMID:  23197426     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
We show that peripheral nitro groups enhance the maximum two-photon absorption cross-section of trans-A(2) B(2) -porphyrins bearing two phenylethynyl substituents by more than one order of magnitude. Maximum values as high as 1000 GM result from realization of suitable conditions for effective resonance enhancement along with a lowering of the energy and intensification of the two-photon allowed transitions in the Soret region.
Authors:
Agnieszka Nowak-Król; Craig J Wilson; Mikhail Drobizhev; Dmitry V Kondratuk; Aleksander Rebane; Harry L Anderson; Daniel T Gryko
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Chemphyschem : a European journal of chemical physics and physical chemistry     Volume:  13     ISSN:  1439-7641     ISO Abbreviation:  Chemphyschem     Publication Date:  2012 Dec 
Date Detail:
Created Date:  2012-11-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100954211     Medline TA:  Chemphyschem     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  3966-72     Citation Subset:  IM    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warsaw (Poland).
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