| Amphoteric alpha-Boryl Aldehydes. | |
| | |
MedLine Citation:
|
PMID: 21809873 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
|
A new class of stable molecules, alpha-boryl aldehydes, has been prepared from oxiranyl MIDA boronates by a 1,2-boryl migration and concomitant epoxide scission. A range of boryl imines, alkenes, alcohols, acids, enol ethers, ena-mides, and other functionalized boronic acid derivatives, difficult or impossible to prepare using established protocols, can be accessed from alpha-boryl aldehydes. The chemoselective transformations of these building blocks, including facile synthesis of functionalized unnatural amino acids from silyloxy and amido vinyl boronates, attest to the potential of alpha-boryl aldehydes in chemical synthesis. |
| | |
Authors:
|
Zhi He; Andrei K Yudin |
Related Documents
:
|
17688933 - Acrylophosphonic acid reactivity with calcium ions and biological apatite. 17898473 - Aquatic risk assessment of 2-sulfonato fatty acid methyl ester sodium salt (mes). 7600443 - Intraluminal ph modulates gastric prostaglandin synthesis. |
Publication Detail:
|
Type: JOURNAL ARTICLE Date: 2011-8-2 |
Journal Detail:
|
Title: Journal of the American Chemical Society Volume: - ISSN: 1520-5126 ISO Abbreviation: - Publication Date: 2011 Aug |
Date Detail:
|
Created Date: 2011-8-3 Completed Date: - Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: - |
Other Details:
|
Languages: ENG Pagination: - Citation Subset: - |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
|
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Measurements of nitrous acid in commercial aircraft exhaust at the Alternative Aviation Fuel Experim...
Next Document: The graphene-gold interface and its implications for nano-electronics.