| Allylcopper intermediates with N-heterocyclic carbene ligands: synthesis, structure, and catalysis. | |
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MedLine Citation:
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PMID: 20000669 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Allylcopper intermediates with N-heterocyclic carbene ligands are synthesized by transmetalation of allylsiloxane reagents, and the crystal structures of allylcopper compounds are reported. The allylcopper transmetalation is utilized for catalytic aldehyde allylation, which is found to be facilitated by a trifluorosilane co-catalyst. |
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Authors:
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Vincenzo Russo; Jessica R Herron; Zachary T Ball |
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Publication Detail:
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Type: Journal Article |
Journal Detail:
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Title: Organic letters Volume: 12 ISSN: 1523-7052 ISO Abbreviation: Org. Lett. Publication Date: 2010 Jan |
Date Detail:
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Created Date: 2010-01-11 Completed Date: 2010-03-08 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: United States |
Other Details:
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Languages: eng Pagination: 220-3 Citation Subset: IM |
Affiliation:
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Department of Chemistry, Rice University, Houston, Texas 77005, USA. |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Aldehydes
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chemistry Catalysis Copper / chemistry* Crystallography, X-Ray Heterocyclic Compounds / chemical synthesis, chemistry* Ligands Methane / analogs & derivatives*, chemical synthesis, chemistry Models, Molecular Molecular Structure Organometallic Compounds / chemical synthesis, chemistry* |
| Chemical | |
Reg. No./Substance:
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0/Aldehydes; 0/Heterocyclic Compounds; 0/Ligands; 0/Organometallic Compounds; 2465-56-7/carbene; 74-82-8/Methane; 7440-50-8/Copper |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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