Document Detail

Allylations of chelated enolates using dienyl substrates.
MedLine Citation:
PMID:  18183999     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Isomerization-free reactions of dienyl carbonates (1-3) with chelated amino acid ester enolates at -78 degrees C provide important information concerning the mechanism of these dienylations. The formation of regioisomeric products can be explained by competing SN2/SN2' reactions, and the product distribution can be influenced by proper choice of the reaction conditions.
Sankar Basak; Uli Kazmaier
Related Documents :
3901019 - Clinical implications of acetaldehyde adducts with hemoglobin.
3155519 - Formation of a beta-aspartyl phosphate intermediate by the vanadate-sensitive atpase of...
11764409 - Activated alumina as an energy source for peptide bond formation: consequences for mine...
10862119 - Reaction competition in the fragmentation of protonated dipeptides
12223879 - S-methylmethionine conversion to dimethylsulfoniopropionate: evidence for an unusual tr...
20434899 - Production of technical grade phosphoric acid from incinerator sewage sludge ash (issa).
10600639 - Characterization of plasma unsaturated lysophosphatidylcholines in human and rat.
20384439 - A biosensor based on zucchini (cucurbita pepo l.) homogenate as a biorecognition layer ...
24726349 - Egg n-3 fatty acid composition modulates biomarkers of choline metabolism in free-livin...
Publication Detail:
Type:  Journal Article     Date:  2008-01-10
Journal Detail:
Title:  Organic letters     Volume:  10     ISSN:  1523-7060     ISO Abbreviation:  Org. Lett.     Publication Date:  2008 Feb 
Date Detail:
Created Date:  2008-01-28     Completed Date:  2008-04-11     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  501-4     Citation Subset:  -    
Universität des Saarlandes, Institut für Organische Chemie, Im Stadtwald, Geb. 23.2, D-66123 Saarbrücken, Germany.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine

Previous Document:  Self-assembly of 1:2 inclusion complexes between a metallocycle host and dihydroxyaromatic guests: a...
Next Document:  Effect of moderate electric field frequency on growth kinetics and metabolic activity of Lactobacill...