| An Alkoxido-Tin-Substituted Polyoxometalate [(MeO)SnW(5) O(18) ](3-) : The First Member of a New Family of Reactive {SnW(5) } Lindqvist-Type Anions. | |
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MedLine Citation:
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PMID: 22147370 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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A SnOW-bound polyoxometalate: Targeted incorporation of {SnOMe}(3+) into lacunary {W(5) O(18) }(6-) has been achieved by hydrolytic self-assembly. The [(MeO)SnW(5) O(18) ](3-) ion undergoes a reversible one-electron reduction, shows a large upfield shift of the W(ax) resonance in the (183) W NMR spectrum and has a calculated HOMO-LUMO gap of 3.5 eV. A wide range of {SnW(5) } derivatives is now accessible by ligand substitution at the Sn centre. |
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Authors:
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Balamurugan Kandasamy; Corinne Wills; William McFarlane; William Clegg; Ross W Harrington; Antonio Rodríguez-Fortea; Josep M Poblet; Peter G Bruce; R John Errington |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-12-6 |
Journal Detail:
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Title: Chemistry (Weinheim an der Bergstrasse, Germany) Volume: - ISSN: 1521-3765 ISO Abbreviation: - Publication Date: 2011 Dec |
Date Detail:
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Created Date: 2011-12-7 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9513783 Medline TA: Chemistry Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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School of Chemistry, Newcastle University, Bedson Building, Newcastle University, Newcastle upon Tyne, NE1 7RU (UK), Fax: (+44) 191-2226929; School of Chemistry, University of St. Andrews, St. Andrews, KY16 9ST (UK). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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