Document Detail


An Alkoxido-Tin-Substituted Polyoxometalate [(MeO)SnW(5) O(18) ](3-) : The First Member of a New Family of Reactive {SnW(5) } Lindqvist-Type Anions.
MedLine Citation:
PMID:  22147370     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A SnOW-bound polyoxometalate: Targeted incorporation of {SnOMe}(3+) into lacunary {W(5) O(18) }(6-) has been achieved by hydrolytic self-assembly. The [(MeO)SnW(5) O(18) ](3-) ion undergoes a reversible one-electron reduction, shows a large upfield shift of the W(ax) resonance in the (183) W NMR spectrum and has a calculated HOMO-LUMO gap of 3.5 eV. A wide range of {SnW(5) } derivatives is now accessible by ligand substitution at the Sn centre.
Authors:
Balamurugan Kandasamy; Corinne Wills; William McFarlane; William Clegg; Ross W Harrington; Antonio Rodríguez-Fortea; Josep M Poblet; Peter G Bruce; R John Errington
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-12-6
Journal Detail:
Title:  Chemistry (Weinheim an der Bergstrasse, Germany)     Volume:  -     ISSN:  1521-3765     ISO Abbreviation:  -     Publication Date:  2011 Dec 
Date Detail:
Created Date:  2011-12-7     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9513783     Medline TA:  Chemistry     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
School of Chemistry, Newcastle University, Bedson Building, Newcastle University, Newcastle upon Tyne, NE1 7RU (UK), Fax: (+44) 191-2226929; School of Chemistry, University of St. Andrews, St. Andrews, KY16 9ST (UK).
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