Document Detail


Advances in the biology and chemistry of sialic acids.
MedLine Citation:
PMID:  20020717     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Sialic acids are a subset of nonulosonic acids, which are nine-carbon alpha-keto aldonic acids. Natural existing sialic acid-containing structures are presented in different sialic acid forms, various sialyl linkages, and on diverse underlying glycans. They play important roles in biological, pathological, and immunological processes. Sialobiology has been a challenging and yet attractive research area. Recent advances in chemical and chemoenzymatic synthesis, as well as large-scale E. coli cell-based production, have provided a large library of sialoside standards and derivatives in amounts sufficient for structure-activity relationship studies. Sialoglycan microarrays provide an efficient platform for quick identification of preferred ligands for sialic acid-binding proteins. Future research on sialic acid will continue to be at the interface of chemistry and biology. Research efforts not only will lead to a better understanding of the biological and pathological importance of sialic acids and their diversity but also could lead to the development of therapeutics.
Authors:
Xi Chen; Ajit Varki
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Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.; Review    
Journal Detail:
Title:  ACS chemical biology     Volume:  5     ISSN:  1554-8937     ISO Abbreviation:  ACS Chem. Biol.     Publication Date:  2010 Feb 
Date Detail:
Created Date:  2010-02-19     Completed Date:  2010-05-10     Revised Date:  2011-07-25    
Medline Journal Info:
Nlm Unique ID:  101282906     Medline TA:  ACS Chem Biol     Country:  United States    
Other Details:
Languages:  eng     Pagination:  163-76     Citation Subset:  IM    
Affiliation:
Department of Chemistry, University of California, Davis, California 95616, USA. chen@chem.ucdavis.edu
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MeSH Terms
Descriptor/Qualifier:
Bacteria / enzymology
Combinatorial Chemistry Techniques
Genetic Engineering
Microarray Analysis
Neuraminidase / chemistry
Polysaccharides / chemistry*
Polysaccharides, Bacterial / chemistry
Sialic Acids* / biosynthesis,  chemical synthesis,  chemistry
Sialyltransferases / chemistry
Grant Support
ID/Acronym/Agency:
P01 HL057345-12/HL/NHLBI NIH HHS; P01HL57345/HL/NHLBI NIH HHS; R01GM076360/GM/NIGMS NIH HHS; U01 CA128442-03/CA/NCI NIH HHS; U01CA128442/CA/NCI NIH HHS
Chemical
Reg. No./Substance:
0/Polysaccharides; 0/Polysaccharides, Bacterial; 0/Sialic Acids; EC 2.4.99.-/Sialyltransferases; EC 3.2.1.18/Neuraminidase
Comments/Corrections

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