Document Detail


Adsorption of benzoic acid, phthalic acid on gold substrates studied by surface-enhanced Raman scattering spectroscopy and density functional theory calculations.
MedLine Citation:
PMID:  23261703     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Benzoic acid (BA) and phthalic acid (PTA) are the simplest aromatic carboxylic acids, and they can be regarded as typical model compounds in investigating the interaction of aromatic carboxylic acids with metal surfaces by use of SERS spectroscopy. In this work, we have investigated the structure and adsorption behavior of benzoic acid and phthalic acid on the gold surface with combination of SERS and DFT calculation methods. The experimental results show that both BA and PTA may be adsorbed on the Au surface with a bidentate bridging structure, namely, the carboxylate group(s) being bound to gold via two oxygen atoms in the carboxylate group(s). Comparison of the observed SERS and predicted spectra of the complexes of these two substances with Au atoms indicates that BA is favorable to adsorb on the gold surface with a vertical orientation rather than a flat one, and PTA could "stand up" on the Au surface as a slight tilt with a two-legged geometry, i.e. all four oxygen atoms in two carboxylate groups interact on the metal surface. Apart from that, we compare the discrepancy of SERS spectra between those two molecules, which could be taken as a potential analysis technique in food safety field.
Authors:
Jiao Gao; Yongjun Hu; Shaoxin Li; Yanjiao Zhang; Xue Chen
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-12-7
Journal Detail:
Title:  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy     Volume:  104C     ISSN:  1873-3557     ISO Abbreviation:  Spectrochim Acta A Mol Biomol Spectrosc     Publication Date:  2012 Dec 
Date Detail:
Created Date:  2012-12-24     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9602533     Medline TA:  Spectrochim Acta A Mol Biomol Spectrosc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  41-47     Citation Subset:  -    
Copyright Information:
Crown Copyright © 2012. Published by Elsevier B.V. All rights reserved.
Affiliation:
MOE Key Laboratory of Laser Life Science & Institute of Laser Life Science, College of Biophotonics, South China Normal University, Guangzhou 510631, China.
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