Document Detail


Adsorption of Ammonia by Sulfuric Acid Treated Zirconium Hydroxide.
MedLine Citation:
PMID:  22686609     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The adsorption of ammonia on Zr(OH)4, as well as Zr(OH)4 treated with sulfuric acid, were examined. The results show that treating Zr(OH)4 with sulfuric acid leads to the formation of a sulfate on the surface of the material, and that the sulfate contributes to the ammonia adsorption capacity through the formation of an ammonium sulfates species. Calcination of Zr(OH)4 decreases the ammonia adsorption capacity of the material and limits the formation of sulfate species. NMR and FTIR results are presented that show the presence of two distinct ammonium species on the surface of the material. The adsorption capacity of the materials is shown to be a complex phenomenon that is impacted by the surface area, the sulfur content, and the pH of the material. The results illustrate that Zr(OH)4, which is known to adsorb acidic gases, can be modifed and used to adsorb basic gases.
Authors:
T Grant Glover; Gregory William Peterson; Jared B Decoste; Mathew A Browe
Related Documents :
18474429 - Changes in the de novo, salvage, and degradation pathways of pyrimidine nucleotides dur...
214409 - An e.s.r. and spin-trapping study of the reactions of the so4- radical with protein and...
21469449 - Oxetanes from the ring contraction of alpha-triflates of gamma-lactones: oxetane nucleo...
22855409 - Neurohistochemistry in molluscan species: focus on extracellular matrix.
19013189 - Development of reagents to study the turkey's immune response: identification and molec...
6195149 - Polyadenylated rna in two filamentous cyanobacteria.
1429659 - Sphingosine-1-phosphate, a metabolite of sphingosine, increases phosphatidic acid level...
9413139 - Enzymatic large-scale production of 2-keto-3-deoxy-d-glycero-d-galacto-nonopyranulosoni...
3660159 - The effect of secretin on duodenogastric reflux in vagotomised dogs.
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-6-11
Journal Detail:
Title:  Langmuir : the ACS journal of surfaces and colloids     Volume:  -     ISSN:  1520-5827     ISO Abbreviation:  -     Publication Date:  2012 Jun 
Date Detail:
Created Date:  2012-6-12     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9882736     Medline TA:  Langmuir     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Antimalarial Activity of Pyrroloiminoquinones from the Australian Marine Sponge Zyzzya sp.
Next Document:  Following the DNA Ligation of a Single Duplex Using Atomic Force Microscopy.