| Activation of dichloromethane by a V(iii) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate. | |
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MedLine Citation:
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PMID: 23282950 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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A V(III) thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a V(III)-Cl species (major one) and a V(IV) binding to a CH(2) containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics. |
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Authors:
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Tzu-Tso Chen; Yu-Sen Chen; Ya-Ho Chang; Jung-Ching Wang; Yi-Fang Tsai; Gene-Hsiang Lee; Tin-Shen Kuo; Hua-Fen Hsu |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-3 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-3 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry, National Cheng Kung University, Tainan 701, Taiwan. konopka@mail.ncku.edu.tw. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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