Document Detail


Acridinium salt-based fluoride and acetate chromofluorescent probes: molecular insights into anion selectivity switching.
MedLine Citation:
PMID:  19799459     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A series of acridinium salt-based probes capable of detecting fluoride and acetate anions via a nucleophilic attack at the C9 position of the acridinium moiety is reported. The formation of corresponding acridane displays drastic changes, in both UV-vis absorption and fluorescence emission. The sensing mechanism is a reversible process upon treating either tetrafluoroborate salt or an acid.
Authors:
Yu-Chen Lin; Chao-Tsen Chen
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Organic letters     Volume:  11     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2009 Nov 
Date Detail:
Created Date:  2009-10-29     Completed Date:  2009-12-31     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  4858-61     Citation Subset:  IM    
Affiliation:
Department of Chemistry, National Taiwan University, Taipei, Taiwan 106, ROC.
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MeSH Terms
Descriptor/Qualifier:
Acetates / analysis
Acridines / chemistry*,  diagnostic use
Anions / analysis
Borates / analysis
Fluorescent Dyes / chemical synthesis*,  chemistry,  diagnostic use
Fluorides / analysis
Molecular Structure
Chemical
Reg. No./Substance:
0/Acetates; 0/Acridines; 0/Anions; 0/Borates; 0/Fluorescent Dyes; 0/Fluorides

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