Document Detail


Brønsted Acid Enhanced Rhodium-Catalyzed Conjugate Addition of Aryl CH Bonds to α,β-Unsaturated Ketones under Mild Conditions.
MedLine Citation:
PMID:  22744877     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Acid test: With a Brønsted acid as the solvent, the rhodium-catalyzed direct addition of aryl CH bonds to α,β-unsaturated ketones was realized under mild reaction conditions. The acid may assist by interceding in the conflict of the two proton-transfer events and averting the substrate inhibition involved in this type of CH addition reaction.
Authors:
Lei Yang; Bo Qian; Hanmin Huang
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-6-28
Journal Detail:
Title:  Chemistry (Weinheim an der Bergstrasse, Germany)     Volume:  -     ISSN:  1521-3765     ISO Abbreviation:  -     Publication Date:  2012 Jun 
Date Detail:
Created Date:  2012-6-29     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9513783     Medline TA:  Chemistry     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (P.R. China), Fax: (+86) 931-496-8129.
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