| Brønsted Acid Enhanced Rhodium-Catalyzed Conjugate Addition of Aryl CH Bonds to α,β-Unsaturated Ketones under Mild Conditions. | |
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MedLine Citation:
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PMID: 22744877 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Acid test: With a Brønsted acid as the solvent, the rhodium-catalyzed direct addition of aryl CH bonds to α,β-unsaturated ketones was realized under mild reaction conditions. The acid may assist by interceding in the conflict of the two proton-transfer events and averting the substrate inhibition involved in this type of CH addition reaction. |
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Authors:
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Lei Yang; Bo Qian; Hanmin Huang |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-6-28 |
Journal Detail:
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Title: Chemistry (Weinheim an der Bergstrasse, Germany) Volume: - ISSN: 1521-3765 ISO Abbreviation: - Publication Date: 2012 Jun |
Date Detail:
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Created Date: 2012-6-29 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9513783 Medline TA: Chemistry Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (P.R. China), Fax: (+86) 931-496-8129. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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