| Acid-Base Jointly Promoted Copper(I)-Catalyzed Azide-Alkyne Cycloaddition. | |
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MedLine Citation:
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PMID: 21793533 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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In this novel acid-base jointly promoted CuAAC, the combination of CuI/DIPEA/HOAc was developed as a highly efficient catalytic system. The functions of DIPEA and HOAc have been assigned, and HOAc was recognized to accelerate the conversions of the C-Cu bond-containing intermediates and buffer the basicity of DIPEA. As a result, all drawbacks occurring in the popular catalytic system CuI/NR(3) were overcome easily. |
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Authors:
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Changwei Shao; Xinyan Wang; Qun Zhang; Sheng Luo; Jichen Zhao; Yuefei Hu |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-7-27 |
Journal Detail:
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Title: The Journal of organic chemistry Volume: - ISSN: 1520-6904 ISO Abbreviation: - Publication Date: 2011 Jul |
Date Detail:
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Created Date: 2011-7-28 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry, Tsinghua University , Beijing 100084, P. R. China. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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