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σ-Accepting Properties of a Chlorobismuthine Ligand.
MedLine Citation:
PMID:  22461148     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
BiZness as usual? Not exactly! The bismuth atom of the tridentate diphosphinobismuthine (o-(Ph(2) P)C(6) H(4) )(2) BiCl behaves as a Z rather than L ligand when in the coordination sphere of late transition metals such as gold. The σ-acceptor behavior of Bi is supported by its disphenoid coordination geometry and theoretical studies, which show a Au→Bi interaction.
Authors:
Tzu-Pin Lin; Iou-Sheng Ke; François P Gabbaï
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-3-27
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  -     Publication Date:  2012 Mar 
Date Detail:
Created Date:  2012-3-30     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department of Chemistry, Texas A&M University, College Station, TX 77843 (USA) http://www.chem.tamu.edu/rgroup/gabbai/
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