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3,6-dioxypyridazine bridged tungsten-tungsten quadruple bonds. Comparisons of electron delocalisation with oxalate bridged compounds.
MedLine Citation:
PMID:  14737342     Owner:  NLM     Status:  PubMed-not-MEDLINE    
Abstract/OtherAbstract:
The preparation and characterisation of the tungsten-tungsten quadruply bonded, 3,6-dioxypyridazine bridged complex [((t)BuCO(2))(3)W(2)](2)([micro sign]-H(2)C(4)N(2)O(2)) and its single electron oxidised radical cation are reported and, when compared with related bridged dimolybdenum complexes, reveal a different mechanism of electronic coupling from that seen in related oxalate bridged systems.
Authors:
Malcolm H Chisholm; Robin J H Clark; Christopher M Hadad; Nathan J Patmore
Publication Detail:
Type:  Journal Article     Date:  2003-11-20
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1359-7345     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2004 Jan 
Date Detail:
Created Date:  2004-01-22     Completed Date:  2004-09-17     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  England    
Other Details:
Languages:  eng     Pagination:  80-2     Citation Subset:  -    
Affiliation:
Department of Chemistry, The Ohio State University, 100 W. 18th Avenue, Columbus, OH 43210-1173, USA. chisholm@chemistry.ohio-state.edu.
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