| 3,6-dioxypyridazine bridged tungsten-tungsten quadruple bonds. Comparisons of electron delocalisation with oxalate bridged compounds. | |
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MedLine Citation:
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PMID: 14737342 Owner: NLM Status: PubMed-not-MEDLINE |
Abstract/OtherAbstract:
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The preparation and characterisation of the tungsten-tungsten quadruply bonded, 3,6-dioxypyridazine bridged complex [((t)BuCO(2))(3)W(2)](2)([micro sign]-H(2)C(4)N(2)O(2)) and its single electron oxidised radical cation are reported and, when compared with related bridged dimolybdenum complexes, reveal a different mechanism of electronic coupling from that seen in related oxalate bridged systems. |
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Authors:
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Malcolm H Chisholm; Robin J H Clark; Christopher M Hadad; Nathan J Patmore |
Publication Detail:
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Type: Journal Article Date: 2003-11-20 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1359-7345 ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2004 Jan |
Date Detail:
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Created Date: 2004-01-22 Completed Date: 2004-09-17 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: England |
Other Details:
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Languages: eng Pagination: 80-2 Citation Subset: - |
Affiliation:
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Department of Chemistry, The Ohio State University, 100 W. 18th Avenue, Columbus, OH 43210-1173, USA. chisholm@chemistry.ohio-state.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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