Document Detail


(3+3)-Cyclodimerization of Donor-Acceptor Cyclopropanes. Three Routes to Six- Membered Rings.
MedLine Citation:
PMID:  21942355     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
An ability of donor-acceptor cyclopropanes to (3+3)-cyclodimerization was disclosed. It was found that Lewis acid-induced transformations of 2-(hetero)arylcyclopropane-1,1-dicarboxylates containing electron-abundant aromatic substituents led to the construction of six-membered cyclic systems. Depending on the substrate properties and the Lewis acid applied three types of products can be obtained: 1) 1,4-diarylcyclohexanes, 2) 1-aryl-1,2,3,4-tetrahydronaphthalenes, or 3) 9,10-dihydroanthracenes.
Authors:
Olga A Ivanova; Ekaterina M Budynina; Alexey O Chagarovskiy; Igor V Trushkov; Mikhail Ya Melnikov
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-9-26
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  -     ISSN:  1520-6904     ISO Abbreviation:  -     Publication Date:  2011 Sep 
Date Detail:
Created Date:  2011-9-27     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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